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For moles, milky spore is the best treatment. It kills the grubs that they feed on and can stay in the soil for several years. Completely biological (safe).
For voles... get a cat. Or, short of that, use castor oil as a repellent (works for moles, too). There are some products that have a water soluble form that you can put in a hose-end sprayer and treat the whole yard.
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Jesse
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